Browsing by Author "Supawan Tantayanon"

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    Improved hydrogen production from dry reforming reaction using a catalytic packed-bed membrane reactor with Ni-based catalyst and dense PdAgCu alloy membrane
    (Elsevier Ltd, 2016) Sarocha Sumrunronnasak; Supawan Tantayanon; Somchai Kiatgamolchai; Thitinat Sukonket; S. Tantayanon; Department of Chemistry, Faculty of Science, Chulalongkorn University, Bangkok, 10330, Thailand; email: supawan.t@chula.ac.th
    A catalytic Pd76Ag19Cu5 alloy membrane reactor packed with 5% Ni/Ce0.6Zr0.4O2 catalyst was adopted in this study to investigate hydrogen production performance from the dry reforming reaction of methane and carbon dioxide. The 1:1 CH4/CO2 feed was introduced to the reactor with 60 mg of the catalyst at a flow rate of 20 ml/min at 550 �C. The effluent gas compositions were examined using an online gas chromatographer (GC). Compared to a conventional reactor without the membrane, the CH4 and CO2 conversions were significantly increased by 3.5-fold and 1.5-fold, respectively. Correspondingly, the overall H2 yield was greatly improved from about 10-35%. Additionally, the hydrogen selectivity increased from 47 to 53%. It is theorized that the in-situ partial hydrogen withdrawal by the membrane mainly caused the dry reforming reaction equilibrium to shift forward and created a hydrogen-deprived environment unfavorable for the competing reversible water-gas shift reaction to take place. � 2015 Hydrogen Energy Publications, LLC.